Volatile surfactants: Characterization and areas of application

Authors
L. A. Tsarkova, T. D. Gurkov
Journal
Curr. Opin. Colloid Interface Sci.
Year
2022
Volume
60
Pages
101592
L. A. Tsarkova, T. D. Gurkov
Curr. Opin. Colloid Interface Sci. 2022
60
101592
Abstract

Amphiphilic aroma molecules, representatives of fragrance molecules, are introduced as dynamic volatile surfactants. Surface tension of their aqueous solutions proves to be a sensitive and revealing quantity, used for assessment of the adsorption-evaporation behavior both under equilibrium conditions and in regimes of no instantaneous equilibrium. Such volatile amphiphiles are characterized by fast adsorption from bulk solution at an air-water interface, on a timescale of tens of microseconds, and exhibit synergetic effect in mixtures with conventional micellar-forming surfactants. Their ability to evaporate from the interface on a time scale of minutes suggests their applications as “temporal” dynamic cosurfactants in technologies involving fast formation of new surfaces. Current challenges concern evaluation of specific material parameters of volatile aroma surfactants in order to enable their selection for targeted applications.